Details
China cas 15696-40-9 factory wholesale OSMIUM CARBONYL at affordable price
- Molecular Formula:C12O12 Os3
- Molecular Weight:906.725
- Melting Point:224 °C(lit.)
- Boiling Point:°Cat760mmHg
- Flash Point:°C
- PSA：0.00000
- Density:g/cm3
- LogP:-2.49600
OSMIUM CARBONYL(Cas 15696-40-9) Usage
InChI:InChI=1/12CO.3Os/c12*1-2;;;
15696-40-9 Relevant articles
Os3(CO)11(BiPh3): The missing link in osmium-bismuth cluster chemistry
Oh, Suat Ping,Li, Ying-Zhou,Leong, Weng Kee
, p. 46 - 48 (2015)
Abstract The room temperature reaction o...
Multicenter transformations of the methyl ligand in CH3Os3Au carbonyl cluster complexes: Synthesis, characterization and DFT analyses
Adams, Richard D.,Luo, Zhongwen,Chen, Mingwei,Rassolov, Vitaly
, p. 95 - 107 (2016)
Os3(CO)11(NCCH3) and Os3(CO)10(NCCH3)2 r...
Reaction of 6-methyl-2,2′-bipyridine with 1,2-Os3(CO) 10(MeCN)2: Syntheses, reductive elimination/ligand displacement kinetics, and X-ray diffraction structures of the isomeric clusters HOs3(CO)9(μ2-N2C 11H9)
Poola, Bhaskar,Carrano, Carl J.,Richmond, Michael G.
, p. 3018 - 3028 (2008)
Treatment of Os3(CO)10(MeCN)2 (1) with t...
Mercury-osmium carbonyl clusters resulting from facile Hg-C bond cleavage: Reactions of [Os3H2(CO)10] with [Hg(C≡CPh)2] and [RHgC≡CHgR] (R = Ph, Me or Et)
Au, Yat-Kun,Wong, Wing-Tak
, p. 899 - 911 (1996)
Reaction of the unsaturated cluster [Os3...
Triosmium and triruthenium clusters containing diazaheterocycles
Agarwala, Razaram,Azam, Kazi A.,Dilshad, Rahima,Kabir, Shariff E.,Miah, Rashid,et al.
, p. 135 - 144 (1995)
The reactions of Os3(CO)11(MeCN) with 1-...
Synthesis, structure, and ligand dynamics of triosmium imidoyl clusters and their isocyanide derivatives
Day, Michael,Espitia, David,Hardcastle, Kenneth I.,Kabir, Shariff E.,McPhillips, Tim,Rosenberg, Edward,Gobetto, Roberto,Milone, Luciano,Osella, Domenico
, p. 2309 - 2324 (1993)
The synthesis of (μ-H)(μ-η2-C=NCH2CH2CH ...
PREPARATION AND SOME REACTIONS OF μ-TRICARBONYLOSMIO-BIS-(4 Os-Os); THE MOLECULAR STRUCTURES OF (OS-Os)>(4 Os-Os)
Farrar, David H.,Johnson, Brian F. G.,Lewis, Jack,Raithby, Paul R.,Rosales, Maria J.
, p. 2051 - 2058 (1982)
The reaction of with carbon monoxide at...
Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene
Tan, Yong Leng Kelvin,Leong, Weng Kee
, p. 768 - 773 (2007)
The heteronuclear cluster RuOs3(μ-H)2(CO...
Synthesis of New Cobalt-Osmium Mixed-metal Clusters using a Novel Reactive Cobalt Species; X-Ray Crystal Structure of
Lewis, Jack,Pardy, Richard B. A.,Raithby, Paul R.
, p. 1509 - 1512 (1982)
Thermal decomposition of the known compl...
A zwitterionic triosmium cluster bearing a metallated azulene ligand coordinated perpendicularly as an alkylidene bridge
De Sanctis, Ysaura,Arce, Alejandro J.,Ca?avera, Farrah,Machado, Ruben,Deeming, Antony J.,González, Teresa,Galarza, Esperanza
, p. 2025 - 2028 (2004)
The cluster [Os3(CO)10(MeCN)2] reacts re...
Synthesis and structure of two tetranuclear osmium carbonyl isotopomers: A crystallographic isotope effect
Canal, John P.,Jennings, Michael,Yap, Glenn P. A.,Pomeroy, Roland K.
, p. 1375 - 1382 (2008)
A synthetic route to [Os4(μ-H)(μ-OH)(μ-C...
Reaction of pyrones with triosmium clusters
Lin, Qi,Leong, Weng Kee
, p. 3639 - 3648 (2003)
A report on the reaction of pyrones with...
Chemical and thermal behavior of the molecular models [Os3(CO)10(μ-H)(μ-OSiR2R′)] (R = Et, Ph; R′ = Et, Ph, OH, OSiPh2OH): Molecular approach to the clarification of the surface chemistry of the silica-anchored cluster [Os3(CO)10(μ-H)(μ-OSi≡)]
Lucenti, Elena,Roberto, Dominique,Ugo, Renato
, p. 1725 - 1733 (2001)
The reactivity (e.g., toward hydrolysis,...
Reactions of diacetylene ligands with trinuclear clusters. I. Reactions of 2,4-hexadiyne-1.6-diol and its dicobalthexacarbonyl derivatives with H2Os3(CO)10
Karpov, M. G.,Tunik, S.P.,Denisov, V.R.,Starova, G.L.,Nikol'skii, A.B.,et al.
, p. 219 - 226 (1995)
Reactions of H2Os3(CO)10 with the diyne ...
Complexation and activation of the bisfulleroid C64H4 with triosmium carbonyl clusters
Lien, Shao-Tang,Yeh, Wen-Yann
, p. 69 - 72 (2012)
Reaction of C64H4 (1) and Os3(CO) 10(NCM...
Products of the Reaction of Carbon Monoxide with ; X-Ray Crystal Structure of
Farrar, David H.,Johnson, Brian F. G.,Lewis, Jack,Nicholls, J. Nicola,Raithby, Paul R.,Rosales, Maria J.
, p. 273 - 274 (1981)
The new clusters and have been prepare...
SIMPLE, HIGH-YIELDS SYNTHESES OF NICKEL-OSMIUM CLUSTERS. SPECTROSCOPIC CHARACTERIZATION OF THE NEW (η-C5H5)NiOs3(C0)9(μ2-H)3. THE REACTIVITY OF (η-C5H5)NiOs3(CO)9(μ2-H)3 AND (η-C5H5)3Ni3Os3(CO)9 TOWARDS H2, CO, ALKYNES AND ALKENES
Castiglioni, Mario,Sappa, Enrico,Valle, Mario,Lanfranchi, Maurizio,Tiripicchio, Antonio
, p. 99 - 112 (1983)
The complexes (η-C5H5)NiOs3(CO)9(μ2-H)3 ...
Synthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligand derived from 9-anthraldehyde oxime
Wong, Janet Shuk-Yee,Lin, Zhen-Yang,Wong, Wing-Tak
, p. 713 - 717 (2003)
Treatment of [Os3(CO)11(MeCN)] with 1 eq...
Synthesis and characterization of triosmium-dipalladium mixed-metal cluster. Crystal structure of
Chan, Suzanna,Wong, Wing-Tak
, p. C78 - C80 (1995)
The cluster reacts with to give 2Os3(C...
Novel higher nuclearity osmium-antimony clusters by alkene- or diene-assisted cluster condensation
Deng, Mingli,Weng, Kee Leong
, p. 1020 - 1023 (2002)
The reaction of the cluster Os3(μ-SbPh2)...
Osmium-antimony higher nuclearity clusters
Leong, Weng Kee,Chen, Guizhu
, p. 2280 - 2287 (2001)
Thermolysis of Os3(CO)11(SbPh3), 1, in r...
Triosmium Clusters derived from Aldehydes, Ketones, and Ketens and their Interconversions
Azam, Kazi A.,Deeming, Antony J.,Rothwell, Ian P.
, p. 91 - 98 (1981)
Acyl and enolato-complexes of types (R ...
The reaction of [Os6(CO)18] with [(SPPh 2)2NH]: Facile rearrangement of the metal framework
Dominguez-Guzman, Karina,Carrasco, Ana L.,Leyva, Marco A.,Rosales-Hoz, Marí J.,Haiduc, Ionel,Silvestru, Cristian
, p. 2661 - 2663 (2010)
The reaction of [Os6(CO)18] 1 with [(SPP...
Potential models of the interactions between nitrogen-containing heterocycles and the active catalyst sites in heterogeneous hydrodenitrogenation catalysts
Eisenstadt,Giandomenico,Frederick,Laine
, p. 2033 - 2039 (1985)
At present, there is no general descript...
NHC complexes of osmium clusters: A structural and reactivity study
Cooke, Craig E.,Jennings, Michael C.,Katz, Michael J.,Pomeroy,Clyburne, Jason A. C.
, p. 5777 - 5799 (2008)
A carbene transfer agent, 1,3-bis-(2,4,6...
Extrusion of selenium and tellurium atoms from selenophene and tellurophene by reaction with trinuclear iron, ruthenium, and osmium clusters: crystal structures of 3-Se)(μ4-C4H3)(CO)20> and of 3-Se)(μ-C4H4)(CO)11>
Arce, Alejandro J.,Machado, Ruben,Rivas, Carlos,Sanctis, Ysaura de,Deeming, Anthony J.
, p. 63 - 75 (1991)
The trinuclear carbonyl clusters , , , a...
A Complete Model for the Catalytic Reduction of an Alkyne to an Alkene by a Trinuclear Osmium Cluster: the X-Ray Crystal Structure of cis->
Dawoodi, Zain,Henrick, Kim,Mays, Martin J.
, p. 696 - 698 (1982)
> reacts with carbon monoxide to give th...
Cage Opening of a Carborane Ligand by Metal Cluster Complexes
Adams, Richard D.,Kiprotich, Joseph,Peryshkov, Dmitry V.,Wong, Yuen Onn
, p. 6501 - 6504 (2016)
The reaction of Os3(CO)10(NCMe)2 with cl...
Metallation of 2-methyl-2-thiazoline at a triosmium cluster: X-ray structure of [(μ-H)Os3(CO)10(μ-η2-CH2C=NCH2CH2S)]
Azam, Kazi A.,Dilshad, Rahima,Kabir, Shariff E.,Mottalib, M.Abdul,Hursthouse, Michael B.,Malik, K.M.Abdul
, p. 1081 - 1084 (2000)
The reaction of [Os3(CO)10(MeCN)2] with ...
Stereospecific coordination of L-hydroxyproline esters with triosmium clusters
Maksakov, V. A.,Kirin, V. P.,Golovin, A. V.
, p. 1941 - 1945 (1995)
The reactions of cluster (μ-H)Os3(CO)10(...
Solid-gas reactions of the "lightly stabilized" Os3(CO)11L (L = NCCH3, C2H4) clusters with CO, NH3, and H2
Aime, Silvio,Dastrù, Walter,Gobetto, Roberto,Krause, Jochen,Sappa, Enrico
, p. 3224 - 3228 (1995)
The solid-gas reactions of the "lightly ...
Stepwise Reduction of CO to CH4 on a Triosmium Cluster Face. Preparation and Characterization of Os3(CO)11CH2
Steinmetz, Guy R.,Geoffroy, Gregory L.
, p. 1278 - 1279 (1981)
-
Non-classical NHC transfers from the reaction of (IMes)AgCl with osmium carbonyl clusters
Cooke, Craig E.,Ramnial, Taramatee,Jennings, Michael C.,Pomeroy, Roland K.,Clyburne, Jason A. C.
, p. 1755 - 1758 (2007)
N-Heterocyclic carbene transfer reaction...
2-[(Diphenylphosphino)methyl]-6-methylpyridine (PN) coordination chemistry at triosmium clusters: Regiospecific ligand activation and DFT evaluation of the isomeric Os3 (CO)10 (PN) clusters
Lin, Chen-Hao,Nesterov, Vladimir N.,Richmond, Michael G.
, p. 24 - 34 (2013/10/01)
The reaction of 2-[(diphenylphosphino)me...
15696-40-9 Process route
-
-
((C6H5)3P)2N(1+)*Os3(CO)10ICH2CO(1-)
-
-
75-64-9
tert-butylamine
-
-
15696-40-9
dodecacarbonyl triosmium
-
-
762-84-5
N-tert-butylacetamide
| Conditions | Yield |
|---|---|
|
With
CO;
In
not given;
under a CO atmosphere, 3 d;
|
35% |
-
-
cis-(μ-1,2-ethanediyl)octacarbonyldiosmium-3,4-d2
-
-
15696-40-9
dodecacarbonyl triosmium
-
-
683-73-8,25549-98-8
Ethylene-d4
| Conditions | Yield |
|---|---|
|
In
octane;
byproducts: cis-ethylene-1,2-d2; under N2; soln. Os-complex/octane heated (130°C, 5 min), soln. turned cloudy and yellow; not isolated, detected by IR spect.; unidentified Os-compd. may also bepresent;
|
<1.8 |
15696-40-9 Upstream products
-
133869-39-3
undecacarbonyl(acetonitrile)triosmium
-
201230-82-2
carbon monoxide
-
15226-74-1
dicobalt octacarbonyl
-
17685-52-8
triiron dodecarbonyl
15696-40-9 Downstream products
-
116261-58-6
Os3(CO)11(PPh3)
-
33635-55-1
Os(CO)3(triphenylphosphine)2
-
119909-83-0
((C6H5)3P)2N(1+)*{Os3Cl(CO)11}(1-)=((C6H5)3P)2N{Os3Cl(CO)11}
-
80800-43-7
(C6H5)3PNP(C6H5)3(1+)*Os3CON(CH3)2(CO)11(1-)
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